Standing
| # | Team | MP | W | D | L | F | A | G | P |
|---|---|---|---|---|---|---|---|---|---|
| 1 | Barcelona | 9 | 8 | 0 | 1 | 28 | 9 | +19 | 24 |
| 2 | Real Madrid | 9 | 6 | 3 | 0 | 19 | 6 | +13 | 21 |
| 3 | Atlético de Madrid | 9 | 4 | 5 | 0 | 13 | 5 | +8 | 17 |
| 4 | Villarreal | 9 | 5 | 2 | 2 | 17 | 17 | +0 | 17 |
| 5 | Osasuna | 9 | 4 | 3 | 2 | 13 | 14 | -1 | 15 |
| 6 | Athletic Bilbao | 9 | 4 | 2 | 3 | 13 | 10 | +3 | 14 |
| 7 | Mallorca | 9 | 4 | 2 | 3 | 9 | 8 | +1 | 14 |
| 8 | Rayo Vallecano | 9 | 3 | 4 | 2 | 11 | 9 | +2 | 13 |
| 9 | Celta Vigo | 9 | 4 | 1 | 4 | 16 | 15 | +1 | 13 |
| 10 | Real Betis | 9 | 3 | 3 | 3 | 8 | 8 | +0 | 12 |
| 11 | Girona | 9 | 3 | 3 | 3 | 11 | 12 | -1 | 12 |
| 12 | Sevilla | 9 | 3 | 3 | 3 | 9 | 10 | -1 | 12 |
| 13 | Alaves | 9 | 3 | 1 | 5 | 11 | 15 | -4 | 10 |
| 14 | Espanyol | 9 | 3 | 1 | 5 | 9 | 13 | -4 | 10 |
| 15 | Real Sociedad | 9 | 2 | 3 | 4 | 7 | 8 | -1 | 9 |
| 16 | Getafe | 9 | 1 | 5 | 3 | 6 | 7 | -1 | 8 |
| 17 | Leganes | 9 | 1 | 5 | 3 | 5 | 9 | -4 | 8 |
| 18 | Valencia | 9 | 1 | 3 | 5 | 5 | 13 | -8 | 6 |
| 19 | Real Valladolid | 9 | 1 | 2 | 6 | 5 | 19 | -14 | 5 |
| 20 | Las Palmas | 9 | 0 | 3 | 6 | 9 | 17 | -8 | 3 |
Fixtures
| October 18, 2024 | ||
| Alaves | 22:00 | Real Valladolid |
| October 19, 2024 | ||
| Athletic Bilbao | 15:00 | Espanyol |
| Osasuna | 17:15 | Real Betis |
| Girona | 19:30 | Real Sociedad |
| Celta Vigo | 22:00 | Real Madrid |
| October 20, 2024 | ||
| Mallorca | 15:00 | Rayo Vallecano |
| Atlético de Madrid | 17:15 | Leganes |
| Villarreal | 19:30 | Getafe |
| Barcelona | 22:00 | Sevilla |
| October 21, 2024 | ||
| Valencia | 22:00 | Las Palmas |
| October 25, 2024 | ||
| Espanyol | 22:00 | Sevilla |
| October 26, 2024 | ||
| Real Valladolid | 15:00 | Villarreal |
| Rayo Vallecano | 17:15 | Alaves |
| Las Palmas | 19:30 | Girona |
| Real Madrid | 22:00 | Barcelona |
| October 27, 2024 | ||
| Leganes | 17:00 | Celta Vigo |
| Getafe | 19:15 | Valencia |
| Real Betis | 21:30 | Atlético de Madrid |
| October 28, 2024 | ||
| Real Sociedad | 00:00 | Osasuna |
| October 29, 2024 | ||
| Mallorca | 00:00 | Athletic Bilbao |
| October 6, 2024 | ||
| Real Sociedad | 1 - 1 | Atlético de Madrid |
| Sevilla | 1 - 0 | Real Betis |
| Alaves | 0 - 3 | Barcelona |
| Girona | 2 - 1 | Athletic Bilbao |
| October 5, 2024 | ||
| Real Madrid | 2 - 0 | Villarreal |
| Real Valladolid | 1 - 2 | Rayo Vallecano |
| Las Palmas | 0 - 1 | Celta Vigo |
| Getafe | 1 - 1 | Osasuna |
| Espanyol | 2 - 1 | Mallorca |
| October 4, 2024 | ||
| Leganes | 0 - 0 | Valencia |
| September 30, 2024 | ||
| Villarreal | 3 - 1 | Las Palmas |
| September 29, 2024 | ||
| Atlético de Madrid | 1 - 1 | Real Madrid |
| Real Betis | 1 - 0 | Espanyol |
| Athletic Bilbao | 1 - 1 | Sevilla |
| Celta Vigo | 1 - 1 | Girona |
| September 28, 2024 | ||
| Osasuna | 4 - 2 | Barcelona |
| Real Sociedad | 3 - 0 | Valencia |
| Rayo Vallecano | 1 - 1 | Leganes |
| Getafe | 2 - 0 | Alaves |
| September 27, 2024 | ||
| Real Valladolid | 1 - 2 | Mallorca |